All-Star Game — July 12, 1966
AL Roster
26 players
| Pos | Player | Team | Played |
|---|---|---|---|
| P | Denny McLain | Detroit Tigers | Yes |
| C | Bill Freehan | Detroit Tigers | Yes |
| 1B | George Scott | Boston Red Sox | Yes |
| 2B | Bobby Knoop | California Angels | Yes |
| 3B | Brooks Robinson HOF | Baltimore Orioles | Yes |
| SS | Dick McAuliffe | Detroit Tigers | Yes |
| LF | Frank Robinson HOF | Baltimore Orioles | Yes |
| CF | Al Kaline HOF | Detroit Tigers | Yes |
| RF | Tony Oliva HOF | Minnesota Twins | Yes |
| — | Andy Etchebarren | Baltimore Orioles | — |
| — | Bobby Richardson | New York Yankees | Yes |
| — | Carl Yastrzemski HOF | Boston Red Sox | — |
| — | Catfish Hunter HOF | Kansas City Athletics | — |
| — | Earl Battey | Minnesota Twins | Yes |
| — | Gary Bell | Cleveland Indians | — |
| — | Harmon Killebrew HOF | Minnesota Twins | Yes |
| — | Jim Fregosi | California Angels | Yes |
| — | Jim Kaat HOF | Minnesota Twins | Yes |
| — | Mel Stottlemyre | New York Yankees | Yes |
| — | Norm Cash | Detroit Tigers | Yes |
| — | Pete Richert | Washington Senators | Yes |
| — | Rocky Colavito | Cleveland Indians | Yes |
| — | Sam McDowell | Cleveland Indians | — |
| — | Sonny Siebert | Cleveland Indians | Yes |
| — | Steve Barber | Baltimore Orioles | — |
| — | Tommie Agee | Chicago White Sox | Yes |
NL Roster
27 players